近海核电厂核素地下水释放通量的模型计算方法     

朱君  李婷  陈超  谢添  张艾明 《吉林大学学报(地球科学版)》2021,51(1):201-211

为了定量计算陵区近海核电站排水管线泄漏情景下核素通过地下水途径向海洋环境的释放通量，以某近海核电站为例进行研究。首先，应用GOCAD软件建立三维地形地质模型，刻画地层的分布、剥蚀以及倾向等特点；然后，运用地下水数值模拟软件FEFLOW精细刻画丘陵区地下水系统的补给、径流和排泄特征；最后，以不被吸附滞留的核素³H和被吸附滞留的核素⁹⁰Sr、¹³⁷Cs为对象，通过实验测定了⁹⁰Sr、¹³⁷Cs在不同岩土介质中的分配系数，模拟计算了排水管线连续渗漏60 a后³H、⁹⁰Sr、¹³⁷Cs在地下水中的放射性分布及释放。结果表明：³H迁移速度基本与地下水流速一致，地下水中的最大放射性浓度为0.285 0 Bq/L，第20 000天时向收纳水域的释放通量达到最大值，约526 Bq/d；⁹⁰Sr吸附性能相对较弱，最大迁移距离约80 m，地下水中的最大放射性浓度为0.032 1 Bq/L；¹³⁷Cs吸附能力较强，相当长的时间内被滞留在管线附近，地下水中最大放射性浓度分别为6.840×10^-3 Bq/L，释放通量为0 Bq/d。由弥散度的不确定分析可知，弥散度越大，地下水中³H的最大放射性浓度越小，向海洋环境的释放通量越多。  相似文献   

Seasonal variation of atmospheric dimethylsulfide at Amsterdam Island in the southern Indian Ocean     

B. C. Nguyen  N. Mihalopoulos  S. Belviso 《Journal of Atmospheric Chemistry》1990,11(1-2):123-141

Daily measurements of atmospheric concentrations of dimethylsulfide (DMS) were carried out for two years in a marine site at remote area: the Amsterdam Island (37°50S–77°31E) located in the southern Indian Ocean. DMS concentrations were also measured in seawater. A seasonal variation is observed for both DMS in the atmosphere and in the sea-surface. The monthly averages of DMS concentrations in the surface coastal seawater and in the atmosphere ranged, respectively, from 0.3 to 2.0 nmol l^-1 and from 1.4 to 11.3 nmol m^-3 (34 to 274 pptv), with the highest values in summer. The monthly variation of sea-to-air flux of DMS from the southern Indian Ocean ranges from 0.7 to 4.4 mol m^-2 d^-1. A factor of 2.3 is observed between summer and winter with mean DMS fluxes of 3.0 and 1.3 mol m^-2 d^-1, respectively.  相似文献   

The ＂CO2-rich gas vents＂ of Mt. Amiata volcano （Tuscany, Central Italy）： Geochemistry,genetic mechanism and hazard evaluation     

Franco Tassi Orlando Vaselli Elena Lognoli Fabrizio Cuccoli Barbara Nisi Elena Ramaldi Sandro Moretti Luca Lombardi Bruno Capaccioni 《中国地球化学学报》2006,25(B08):70-71

Mt. Amiata （Southern Tuscany, Central Italy） is an extinct Quaternary volcano located in an area still marked by high heat-flow that is caused by deep seated （6-10 km） hot masses related to Pliocene magmatic activity. The anomalous geothermal gradient gives rise, within the Mesozoic limestone formation （Tuscan series）, to geothermal systems that fed the Ca-SO4 thermal springs characterizing this area. Besides of thermal fluids, several cold, dry CO2-rich gas emissions seep out on the NE flank of the volcano. These gas vents mostly consist of large sub-circular craters at variable depth and diameter （5-15 m and 10-50 m, respectively）, and represent a serious hazard for the local population, as testified by the several asphyxia casualties that have been repeatedly occurred within these morphological depressions. In this work, the chemical and isotopic compositions of the Mt. Amiata ＂CO2-rich gas vents＂ and the estimation of both the CO2 flux from the soil and the CO2 distribution in air of their surroundings, has been carried out in order to： （1） assess the origin of gases, （2） recognize the mechanism of formation for these gas emissions and their relationship with local tectonics, and （3） to evaluate the CO2 hazard in the high flux emanations. The chemical composition of the gases is largely dominated by CO2 （up to 98 % by vol） and shows relatively high concentrations of N2, CH4 and H2S （up to 1.1%, 0.9% and 3.9 % by vol, respectively）. These features, coupled with the carbon and nitrogen isotopic signatures, suggest that the origin of the main gas compounds may be related to the contribution of deep （i.e., thermometamorphic processes on carbonate formations for CO2） and shallow （i.e. thermal decomposition of organic material for CH4, N2 and H2S） sources.  相似文献   

Total gaseous mercury emissions from mercury-enriched soil in Guizhou, China     

Xinbin FENG Shaofeng WANG Guangle QIU Yamin HOU Shunlin TANG 《中国地球化学学报》2006,25(B08):243-244

Guizhou is located in the Circum-Pacific Global Mercuriferous Belt, and mercury concentrations in soil in this area are enriched. In-situ total gaseous mercury （TGM） exchange fluxes between air and soil surface were intensively measured at four sampling sites in Guiyang from 21 May to 16 June, 2003, and five sites in the Lanmuchang mercury mining area in December 2002 and May 2003, respectively. The in-situ Hg flux measurement was conducted with a dynamic flux chamber （DFC） of quartz. Overall, net emissions were obtained from all sampling sites. Soil mercury concentration and solar radiation have been proved to be the two most important parameters to control mercury emissions from soil. Meanwhile, rain events can enhance mercury emission rate significantly.  相似文献   

Palaeovariations in the East-Asian Monsoon Regime Geochemically Recorded in Varved Sediments of Lake Sihailongwan (Northeast China, Jilin Province). Part 2: a 200-Year Record of Atmospheric Lead-210 Flux Variations and its Palaeoclimatic Implications     

Georg Schettler  Jens Mingram  Jörg F. W. Negendank  Liu Jiaqi 《Journal of Paleolimnology》2006,35(2):271-288

Palaeovariations of the atmospheric ²¹⁰Pb flux in Northeast China (Long Gang area, Jilin province), quantified by high resolution ²¹⁰Pb measurements on seasonally laminated sediments of Lake Sihailongwan are presented on decadal scale. The mean flux of unsupported ²¹⁰Pb between 1790 and 1970 for the centre of the lake basin is 517 Bq m⁻² yr⁻¹ with maximum deviations between −23% and +27% of this value. Flux rates above this average were found between 1783 and 1813, around 1836, and between 1860 and 1901. The mean ²¹⁰Pb^exc flux rates derived were clearly lower around 1821, 1908, 1930, and 1953. The ²¹⁰Pb^exc flux reached its minimum of 344 Bq m⁻² yr⁻¹ during the period 1977–1982. The atmospheric flux of unsupported ²¹⁰Pb is correlated with the precipitation frequency during the summer monsoon and shows coinciding variability with geochemical proxies that document the groundwater inflow into the lake. Al₂O₃-rich dust of remote provenance scavenged by wet-deposition in the rainy season is the major carrier of the atmospheric ²¹⁰Pb^exc flux.  相似文献   

Palaeovariations in the East-Asian Monsoon Regime Geochemically Recorded in Varved Sediments of Lake Sihailongwan (Northeast China, Jilin Province). Part 1: Hydrological Conditions and Dust Flux   总被引：2，自引：0，他引：2  

Georg Schettler  Qiang Liu  Jens Mingram  Jörg F. W. Negendank 《Journal of Paleolimnology》2006,35(2):239-270

The varved sediments of the dimictic Lake Sihailongwan (Long Gang mountain area, Jilin Province, Northeast China) represent a palaeoclimatic archive which documents the local precipitation frequency during the summer monsoon, and variations in the aeolian flux of dust with their remote sources in the arid and semi-arid regions of inner Asia. Based on a detailed discussion of sediment genesis in Lake SHL, dust flux rates and palaeohydrological conditions were reconstructed on a decadal scale over the past 220 years. The aeolian influx by dry and wet deposition was quantified and characterised in its chemical composition. Photosynthetic production in the lake is positively correlated with the inflow of nutrient-rich groundwater. The groundwater discharge largely reflects the strength of the summer monsoon. Net accumulation rates for biogenic silica were determined for annually laminated sediments from the centre of the U-shaped lake basin based on sediment data. In a Si-balance model of the modern lake, the depositional flux of biogenic silica could be independently quantified on the base of hydrochemical monitoring data. Comparison of the both estimates allowed to asses the focussing of the particle flux in the lake. Though water retention in Lake SHL is rather high (ca. 30 years), changes in the hydrological conditions are sensitively recorded in the sediments because (i) nutrient-rich groundwater discharges into the productive zone of the lake, (ii) a substantial proportion of the total dissolved Si-inventory of the mixed lake (ca. 30%) is annually consumed by diatom growth, and (3) sediment accumulation is substantially focussed towards the flat bottom of the lake basin. The bulk siliciclastic sediment fraction (ca. 75 wt.%) largely originates from influx of dust of remote provenance. In sediment thin-sections, the dry-deposited dust fraction is microscopically identifiable as seasonal silt layer. Aeolian input by wet-deposition shows a distinctly higher variability than the influx of dust by dry-deposition. As diatom production, wet-deposition of dust is positively correlated with the rainfall during the summer monsoon. The inferred positive correlation between rainfall and dust flux during the summer monsoon implies that dust deposition is determined by the out-wash efficiency of mineral particles for a permanent high atmospheric dust concentration over Northeast China in the last 220 years.  相似文献   

胞外聚合物对膜生物反应器运行性能的影响   总被引：3，自引：1，他引：3  

张凤君  王顺义  邓锡斌  赵芝清  沙娜  王鹤 《吉林大学学报(地球科学版)》2006,(Z1)

膜生物反应器处理污水过程中,依据胞外聚合物(EPS)、蛋白质、多糖、粘度等参数随时间的变化趋势以及对膜通量的影响,求出上述参数及蛋白质/多糖的比值与膜通量间的相关系数分别为0.28、0.57、0.38、0.14、0.70。结果表明:蛋白质/多糖的比值与膜通量的衰减速度两者相关系数最大。  相似文献   

Application of membrane technology for water treatment： Ultrasound-associated cleaning of fouled microfiltration membranes     

Rui CHEN Xiaoli WANG Yonggang ZHANG Xueqi FU 《中国地球化学学报》2006,25(B08):128-129

The use of membranes is a widely employed, versatile, and effective separation process. One of the limiting aspects in applying microfiltration （MF） for wastewater treatment is that of problems with membrane fouling and consequent flux reduction. Membrane fouling occurs by the irreversible deposition of retained particles, colloids, macromolecules, salts, etc. at the membrane surface and/or inside the membrane. The predominant fouling mechanisms observed with MF membranes are classified as three categories： the build-up of a cake layer on the membrane surface, blocking of membrane pores, and adsorption of fouling material on the membrane surface or in the pore walls. Although many techniques have been developed to overcome fouling, studies on membrane cleaning still seem to be insufficient for practical membrane filtration systems. Current membrane cleaning technologies include hydraulic, chemical, and mechanical methods. Ultrasound （US） has been widely used as a method of cleaning materials because of the cavitation phenomenon. In this study, US cleaning technique was applied to removing the fouling of polyvinglidenefluoride （PVDF） MF membrane, which was used to treat yeast cell and isolated soybean protein （ISP） solution, respectively. The US employed 40 kHz frequency and the output power of 1.43-2.85 W/cm^2. The evolution of the cleaning effect is followed by the measurements of the flux recovery rate （FRstat） and the cleaning time cycle. Results showed that the membrane property, which was fouled by yeast cell solution, could be recovered by water cleaning with US irradiation. And the cleaning time with the same FRstat decreased with the increase of US intensity.  相似文献   

长江三角洲地区水和热通量的时空变化特征及影响因子   总被引：9，自引：2，他引：9  

刘晶淼  周秀骥  余锦华  丁裕国 《气象学报》2002,60(2):139-145

文中利用改进的K B模式和牛顿扩散方法及 196 1年以来的长江三角洲 (2 8～ 33°N ,118～ 12 3°E)地区的 4 8个测站的常规气象资料 ,估计了该地区近 4 0a来的蒸散量和感热通量。结合该地区的气温、太阳辐射等气候资料和 196 0年以来该区域土地资源利用变化等有关信息对该地区的潜热通量和感热通量的时 空间变化特征及其可能成因进行了综合分析。结果认为该地区自 2 0世纪 70年代开始平均蒸散量有逐渐减小的趋势 ,与 1980年相比 ,1998年区域年平均蒸散量减小了 2 4mm。区域平均感热通量与蒸散量相比在此期间变化并不明显。通过对该地区的云量、太阳辐射及土地利用变化资料分析认为 ,造成该地区平均蒸散量减少趋势的的原因之一是用于蒸发的能量即太阳辐射的减少 ,而造成太阳辐射减少的可能原因为云量及大气透明度的变化所至 ;原因之二是该地区地表覆盖条件的改变。近 2 0a来 ,该地区的水田、旱地及水域面积占总面积的比率分别减少 1.35 3% ,4 .4 4 2 %和2 .5 97% ,而城镇建设、工矿及其它建设用地面积则增加 3.345 %。耕地及水面的减小和城镇及建设用地面积的增加从整体上使区域平均蒸发量减少。  相似文献   

青藏高原近地层通量特征的合成分析   总被引：17，自引：0，他引：17  

李国平  段廷扬  巩远发  卢会国 《气象学报》2002,60(4):453-460

利用中日亚洲季风机制合作研究计划 ,设置在青藏高原东部地区的拉萨、日喀则、那曲和林芝 4地 1993年 7月～ 1999年 3月近 7a的自动气象站 (AWS)近地层梯度观测资料 ,确定出分季节的高原地表粗糙度和逐日的地面总体输送系数 ,以此为基础用总体输送公式对地面动量、感热和潜热通量进行了计算 ,并用合成方法分析了 1993～1999年高原近地层通量夏季、冬季的日变化和月变化特征  相似文献